Parameter
Potential Technology

Sulfur, Nitrogen, Density

X-ray Fluorescence (XRF)

O₂, CO

Zirconia O₂ + NDIR CO

H₂S, NH₃

TDLAS + Electrochemical

H₂ purity, H₂S

Micro-GC

H₂S in gas, HC in liquid

UV Fluorescence

H₂S, H₂ concentration

Process GC

H₂S, Water Content

Sulfur Chemiluminescence

Liquid carryover

Near-Infrared

Sulfur, API gravity

FT-NIR Spectroscopy

Description

The FCC feed hydrotreater allows Vacuum Gas Oil to be hydrodesulphurised prior to feeding the FCC. This results in products that are lower in sulphur for blending to final product specifications (notably gasoline blending specifications).

VGO (Vacuum Gas Oil) from VDU is routed to the VGO Hydrotreater Unit for removal of Sulphur and other contaminants to extract maximum benefit from the downstream FCC unit where this treated VGO is converted to high value products. Products from an FCC which process hydrotreated VGO are of better quality than those from non-hydrotreated feedstock.The VGO hydrotreater operates essentially as any hydrotreater operation. Oil is combined with hydrogen and heated to @ 650°F (about 350°C), then sent through a fixed bed reactor. Sulphur and nitrogen compounds are removed from the oil and reacted into hydrogen sulphide and ammonia, respectively. Hydrogen is recompressed and recycled to the front of the unit. The primary differences between hydrotreaters operating on different feeds are operating pressure, the amount of catalyst, and hydrogen recirculation and make-up requirements. The VGO hydrotreater is normally operating at higher pressure than naphtha and diesel hydrotreaters.