Parameter
Potential Technology
Sulfur, Nitrogen, Density
X-ray Fluorescence (XRF)
O₂, CO
Zirconia O₂ + NDIR CO
H₂S, NH₃
TDLAS + Electrochemical
H₂ purity, H₂S
Micro-GC
H₂S in gas, HC in liquid
UV Fluorescence
H₂S, H₂ concentration
Process GC
H₂S, Water Content
Sulfur Chemiluminescence
Liquid carryover
Near-Infrared
Sulfur, API gravity
FT-NIR Spectroscopy
Parameter
Sulfur
Nitrogen
Metals
Potential Technology
X-ray Fluorescence (XRF)
X-ray Fluorescence (XRF)
X-ray Fluorescence (XRF)
Parameter
O₂
CO (flue gas)
Potential Technology
Zirconia O₂ + NDIR CO
Zirconia O₂ + NDIR CO
Parameter
H₂S
H₂S
H₂ Concentration
Water Content
Potential Technology
Process GC
Process GC
Sulfur Chemiluminescence
Sulfur Chemiluminescence
Description
The FCC feed hydrotreater allows Vacuum Gas Oil to be hydrodesulphurised prior to feeding the FCC. This results in products that are lower in sulphur for blending to final product specifications (notably gasoline blending specifications).
VGO (Vacuum Gas Oil) from VDU is routed to the VGO Hydrotreater Unit for removal of Sulphur and other contaminants to extract maximum benefit from the downstream FCC unit where this treated VGO is converted to high value products. Products from an FCC which process hydrotreated VGO are of better quality than those from non-hydrotreated feedstock.The VGO hydrotreater operates essentially as any hydrotreater operation. Oil is combined with hydrogen and heated to @ 650°F (about 350°C), then sent through a fixed bed reactor. Sulphur and nitrogen compounds are removed from the oil and reacted into hydrogen sulphide and ammonia, respectively. Hydrogen is recompressed and recycled to the front of the unit. The primary differences between hydrotreaters operating on different feeds are operating pressure, the amount of catalyst, and hydrogen recirculation and make-up requirements. The VGO hydrotreater is normally operating at higher pressure than naphtha and diesel hydrotreaters.