Parameter
Potential Technology

SO₂, NOx, CO

UV, NDIR

pH, Conductivity, Oils

Electrochemical + UV

Olefins, Sulfur

Near-Infrared

Sulfur, Polyaromatics

X-ray Fluorescence

H₂S, Light Ends

Process GC

Density

XRF

CO/CO₂ Ratio

TDLAS

H₂, CH₄, C2-C5

GC

O₂, CO

Zirconia + NDIR

Catalyst Activity (Coke %)

Raman Spectroscopy

O₂ Purity, Moisture

Paramagnetic O₂ + Hygrometer

CO/CO₂, SO₂

TDLAS (CO/CO₂) + UV DOAS (SO₂)

Description

The Fluidised Catalytic Cracking (FCC) unit cracks heavier hydrocarbons into lighter transport fuels. Carbon, in the form of coke, lays down on the zeolite catalyst used in the unit and rapidly deactivates the catalyst. To mitigate this, the catalyst is kept in a fluidised state which allows it to be transported to the regenerator, in which the coke is burnt off the catalyst using air, and the catalyst is then returned to the riser. The reaction products disengage from the catalyst via cyclones at the top of the reactor vessel. The reactions in FCC units are endothermic but heat balance operation is maintained using the heat of the coke that is combusted in the Regenerator. The products from an FCC are high in aromatics and unsaturated olefins. As a result, FCC units tend to have lower diesel and higher gasoline yields than hydrocrackers. Product qualities also tend to be better for the gasoline products (cracked naphtha) than the diesel range material (light cycle oil). LPG olefins can be used to make alkylate.

The main fractionator produces fuel gas, LPG, a heavy naphtha cut, light cycle oil (LCO) and FCC Slurry. A slurry backwash filter system can also be provided.

The key to treating FCC gasoline is in the ability to achieve the required sulphur reduction whilst maintaining octane levels.