Parameter
Potential Technology
H₂S
TDLAS / UV photometry
Total sulfur
UV fluorescence / micro-GC
Moisture
TDLAS or Aluminum Oxide sensor
H₂S (breakthrough)
TDLAS / UV photometry
O₂ (trim/safety)
Zirconia O₂
NOₓ, SO₂, CO, O₂
CEMS (NDIR/UV + ZrO₂)
Dust/opacity
Opacity/PM monitor
CO, CO₂, CH₄, H₂
Process GC
CO, CO₂, H₂
Process GC
CO, CO₂, CH₄, N₂, H₂
Process GC
Purity (H₂ %, O₂, N₂, CO, CO₂, CH₄)
Process GC
Heating value (BTU)
Calorimeter or micro-GC
Parameter
H₂S
Total sulfur
Moisture
Potential Technology
TDLAS / UV photometry
UV fluorescence / micro-GC
TDLAS or Aluminum Oxide sensor
Parameter
NOₓ, SO₂, CO, O₂
Dust/opacity
Potential Technology
CEMS (NDIR/UV + ZrO₂)
Opacity/PM monitor
Parameter
Heating value (BTU)
H₂S
Potential Technology
Calorimeter or micro-GC
TDLAS / UV photometry
Description
Hydrogen can be produced from a wide range of feedstocks. Methods to produce hydrogen from natural gas are well-developed and account for half of hydrogen production globally. The majority of units are based on steam methane reforming (SMR). The first step of the SMR hydrogen process is the feedstock pre-treatment, where traces of catalyst poisons such as sulphur, chlorine and volatile transition element metals are removed from the feed using a combination of hydrotreating catalyst and zinc oxide.
Hydrogen purification is accomplished in the Pressure Swing Adsorption (PSA) unit. The PSA technology makes use of the physical phenomena that the feed gas components (beside hydrogen) are adsorbed on the adsorption material at a high pressure. The PSA process works at basically constant temperature and uses the effect of alternating pressure and partial pressure to perform adsorption and desorption