Parameter
Potential Technology
H₂, CO, CO₂
Micro-Gas Chromatograph (μGC)
H₂S concentration
TDLAS (Tunable Diode Laser)
Density
Near-Infrared (NIR) Spectroscopy
O₂, CO
Zirconia O₂ + NDIR CO
H₂S, Total Sulfur
Total Sulfur Analyzer (UV Fluorescence or XRF)
Total Sulfur, Mercaptans
Sulfur Chemiluminescence
Heating Value (BTU/scf), H₂S
Calorimeter
Sulfur
X-ray Fluorescence (XRF)
Sulfur, Nitrogen, Aromatics
Fourier-Transform NIR (FT-NIR)
Parameter
H₂
CO
CO₂
Potential Technology
Micro-Gas Chromatograph (μGC)
Micro-Gas Chromatograph (μGC)
Micro-Gas Chromatograph (μGC)
Parameter
Total Sulfur
Mercaptans
Potential Technology
Sulfur Chemiluminescence
Sulfur Chemiluminescence
Parameter
Sulfur
Nitrogen
Aromatics
Potential Technology
Fourier-Transform NIR (FT-NIR)
Fourier-Transform NIR (FT-NIR)
Fourier-Transform NIR (FT-NIR)
Description
Full range naphtha is treated in the Naphtha Hydrotreater (NHT) followed by separation in a Naphtha Splitter. This will produce treated light naphtha for the light Naphtha Isomerisation unit and control sulphur and nitrogen in the heavy naphtha to prevent poisoning of catalysts in the downstream Reforming unit.
The feed naphtha is mixed with a hydrogen-rich recycle gas stream and fed to the feed-effluent exchanger and fired charge heater. The reactor effluent mixture is then cooled and the vapour, hydrocarbon liquid and sour water are separated in the product separator. The vapour and sour water pass to the recycle gas compressor and sour water stripper respectively while the hydrocarbon liquid from the separator is preheated and fed to the stripper column.
The net overhead vapour and sour LPG from the stripper column is sent to the saturated gas plant while the net bottoms (unstabilised naphtha) from the stripper column are cooled and then sent to the Naphtha Splitter (NS) where C6 and lighter hydrocarbons are removed as an overhead liquid light naphtha product resulting in a splitter bottoms of stabilised naphtha to be fed to downstream units.
The C6 hydrocarbon split is managed to minimise the benzene precursors in the feed to the Reformer. This ultimately is a route to controlling benzene in the reformate which is important to meeting the final gasoline product specification.