Parameter
Potential Technology

H₂S/SO₂ Ratio (2:1)

UV-DOAS

COS/CS₂

FT-IR

H₂S, SO₂, Sₓ Vapour

Laser Spectroscopy (TDLAS)

H₂S (<0.5 vol%)

Electrochemical Cell

Liquid Sulfur Purity

X-ray Fluorescence (XRF)

Total Sulfur (H₂S+SO₂)

UV Fluorescence

SO₂ (ppm)

CEMS (NDIR+UV)

H₂S (dissolved)

Colorimetric Analyzer

Purity (99.9%)

NIR Spectroscopy

Liquid Hydrocarbons (BTEX), H₂S

Near-Infrared (NIR) Analyzer

H₂O carryover, NH₃ slip

Moisture Analyzer + Laser NH₃

Description

The Sulphur Recover Unit (SRU) or Claus Process has been developed to recover elemental sulphur from H2S/NH3-containing gases originating from gas treating plants such as Sour Water Strippers. There are two main varieties of the Claus process: straight through and split flow. The straight through process is used for feed gas containing more than 50% H2S, while split flow is applied for gases containing 50 to 15% H2S. The sulphur recovery process consists of a thermal stage (combustion chamber, waste heat boiler) and two or three catalytic reaction stages (reheater, reactor and condenser).

The Claus process is based on the combustion of part of the H2S to SO2 and the subsequent reaction between the remaining H2S and the SO2 produced, forming sulphur. In the thermal stage, the Claus reaction takes place at a high temperature level (950-1350°C). The sulphur produced in this stage is condensed either in the waste heat boiler or in the condenser. Subsequently, the gas is reheated to a temperature of 200-300°C before introduction into each reactor stage. The heat generated from the reactions is used for low, medium, or high steam production. In the sulphur condensers low pressure steam is generated. The tail gas is sent to an incinerator or tail gas treater.

Depending on the number of reactors and the quality of the feed gas, sulphur recoveries may vary from 95 to 98% weight recovery. To increase the sulphur recovery, the tail gas is sent to the Tail Gas Treatment Unit (TGTU), which removes the remaining sulphur by a combination of chemical reaction and absorption. Incinerated tail gas is discharged to the atmosphere through an elevated stack.